Preheat the oven to 180°C/160°C Fan (350˚F). Lightly grease a deep 20 cm (8 in) round cake tin (pan) and line the base with baking parchment.
To make the cake, put the milk, sugar, oil and vinegar in a large jug and whisk until smooth.
Brown sugar, especially unrefined versions which contain higher levels of molasses, can be lumpy, so sift it before using if needed.
Place the remaining ingredients in a large bowl and whisk together to combine. Pour the liquid
ingredients into the dry ingredients and stir with a whisk just until a smooth cake batter is formed. If using rye flour, it is doubly important not to over whisk the batter; rye flour can become gummy if mixed for too long. Pour into the prepared tin and bake for 35–40 minutes or until the cake springs back to a light touch and is coming away from the sides of the tin.
Remove from the oven and allow to cool for 10 minutes before turning out onto a wire rack to cool completely.
To make the ganache, put the chocolate in a small heatproof jug and melt (see page 24). Put the sugar and water in a small saucepan, place over a medium heat and cook, covered with a lid, until the sugar has dissolved and the water has just come to a simmer. Pour a third of the syrup over the chocolate and stir to combine. Pour in the remaining syrup, in two additions, stirring until the mixture forms a silky-smooth ganache. Add the coconut oil and stir to combine.
Once made, the ganache should have a thick but pourable consistency. If the ganache seems thin, leave for about 15 minutes, until thickened slightly. Pour the ganache over the cake, allowing the excess to drip down the sides.
Kept covered, this cake will keep for 4–5 days.